2026
| 231 | Hot-Carrier Injection and Millisecond Charge Separation from a Robust Heteroleptic Iron(II) Chromophore Immobilized on TiO2 T. Whittemore, M. Schmalle, E. Ryndin, M. Spitler, E. H. P. Brohmer, S. Rau, L. Zedler, E. O. Danilov, F. N. Castellano, S. Kupfer, G. Meyer, D. Sorsche, J. Am. Chem. Soc., 2026, accepted |
| 230 | Scanning Photoelectrochemical Microscopy for the Investigation of Local Photocatalytic H2 Evolution in Matrixed Langmuir Films S. Horn, G. Caniglia, S. J. Finkelmeyer, G. Neusser, C. Mankel, B. Bagemihl, S. Rau, C. Neumann, A. Turchanin, R. Müller, K. Leopold, S. Akther, A. Pannwitz, S. Zechel, M. D. Hager, U. S. Schubert, M. Jahn, C. Streb, M. Presselt, C. Kranz, ACS Appl. Mater. Interfaces 2026, accepted |
| 229 | Rational Optimization of Self-Reporting Alcohol-Oxidizing RhIII Complexes L. Hefty, G. Caniglia, M. Abdel-Hamied, A. K. Mengele, C. Kranz, S. Rau, Eur. J. Inorg. Chem., 2026, e70202 |
| 228 | Phenothiazine redox mediators boost photocatalytic hydrogen evolution D. Baumgarten, M. Gollasch, Y. Gupta, M. Jahn, A. K. Mengele, S. Rau, C. Streb, B. Esser, EES Catal., 2026 |
| 227 | Soft-Matter Confinement Modulates Excited-State Dynamics of Ru Photocatalysts for Hydrogen Evolution in Aqueous Media J. H. Tran, N. Vashistha, A. Edwards, A. K. Mengele, A. Koba, S. Ullah, J. Bauer, J. Griebel, M. Schmitt, S. F. El-Mashtoly, J. Popp, D. Ziegenbalg, B. Dietzek-Ivanšić, S. Rau, M. Anjass, ACS Mater. Au 2026, accepted |
| 226 | A Water-soluble Copolymer for Storage and Electron Conversion in Photocatalytic On-demand Hydrogen Evolution M. Hartkorn, R. Kampes, F. Müller, L. Zedler, A. Edwards, P. Rohland, A. K. Mengele, S. Zechel, M. D. Hager, B. Dietzek-Ivanšić, M. Schmitt, J. Popp, U. S. Schubert, S. Rau, Nat. Commun., 2026, 17, 1141 |
| 225 | A Donor-Acceptor Photosensitizer-catalyst Dyad for Light-Driven Nicotinamide Hydrogenation A. Tombrink, M. Semwal, T. Maisuradze, A. K. Mengele, D. Straub, A. Kuehne, S. Rau, S. Kupfer, B. Dietzek-Ivanšić, B. Esser, Chem. Sci., 2026, 17, 3012-3022 |
| 224 | Tailored GAFF Parameters for Pentamethylcyclopentadienyl Rh(I/III) Complexes with α-Diimine Ligands: Validation and Solvation Studies R. Jacobi, K. P. Zois, A. K. Mengele, S. Rau, L. González, J. Phys. Chem. B, 2026, 130, 472-485 |
2025
| 223 | Tailored Photoactivity of 2D Nanosheets Synthesized by Electron Irradiation of Metal-Organic Ru(II) Monolayers M. Küllmer, A. K. Mengele, J. Kund, R. Leiter, F. Herrmann-Westendorf, D. Hüger, R. Gläßner, E. Najafidehaghani, H. R. Rasouli, C. Neumann, J. Biskupek, L. S. Dröge, V. Müller, K. Witas, M. Presselt, T. Weimann, B. Dietzek-Ivanšić, U. Kaiser, C. Kranz, S. Rau, A. Turchanin, Nanoscale, 2025, 17, 24715-24725 |
| 222 | Excited State Branching Processes in a Ru(II)-based Donor-Acceptor-Donor System G. Yang, L. Blechschmidt, L. Zedler, C. Zens, K. Witas, M. Schmidt, B. Esser, S. Rau, G. E. Shillito, B. Dietzek-Ivanšić, S. Kupfer, Chem. Eur. J. 2025, 31, e202404671 |
| 221 | Role of Spacers in Molecularly Linked RuRh Dyads: A Comparative Synthetic and Ultrafast Spectroscopic Investigation M. Semwal, M. Lämmle, E. H. P. Brohmer, S. Volk, L. Zedler, S. Kupfer, A. K. Mengele, G. E. Shillito, S. Rau, B. Dietzek-Ivanšić, Inorg. Chem. 2025, 64, 15, 7273-7285 |
| 220 | In situ formation of an active oxygen evolution catalyst via photodegradation of [Ru(bpy)3]2+ M. Langer, A. K. Mengele, R. Müller, J. C. Wetzel, J. Mayer, S. Rau, C. Streb, Dalton Trans. 2025, 54, 4861-4865 |
| 219 | Ligand labilization gates intramolecular electron transfer in molecular photocatalyst L. Blechschmidt, L. Zedler, A. K. Mengele, S. Rau, B. Dietzek-Ivanšić, Chem. Commun. 2025, 61, 2508-2511 |
| 218 | Shifting the MLCT of d6 metal complexes to the red and NIR D. Sorsche, M. A. L. Lima, N. Meitinger, K. Prasad, S. Mandal, K. D. Glusac, S. Rau, A. Pannwitz, Coord. Chem. Rev. 2025, 530, 216454 |
| 217 | An Increase in the Rigidity of the Environment Favors MLCT over the MC State in [Ru(bpy)2(Nicotine)2](Cl)2: A Case Study of Photolabile Ligands M. Semwal, N. Vashistha, S. Rau, B. Dietzek-Ivanšić, J. Phys. Chem. A 2025, 129, 439-446 |
2024
| 216 | Steering Photoinduced Electron Transfer in Intramolecular Photocatalysts by Peripheral Ligand Control B. Bagemihl, C. Müller, G. E. Shillito, M. Hartkorn, A. K. Mengele, S. Kupfer, B. Dietzek-Ivanšić, S. Rau, ChemistryEurope 2024, e202300084. |
| 215 | Block copolymer micelles as colloidal catalysts for photocatalytic NAD+ reduction J. Eichhorn, A. K. Mengele, C. Neumann, J. Biskupek, A. Turchanin, U. Kaiser, S. Rau, F. H. Schacher, Polym. Chem., 2024, 15, 4810-4823 |
| 214 | Active Molecular Units in Metal Organic Frameworks for Artificial Photosynthesis S. Mandal, S. Yoosefi, A. K. Mengele, S. Rau, A. Pannwitz, Inorg. Chem. Front. 2024, 11, 7682-7755 |
| 213 | Beyond the First Coordination Sphere ─ Manipulating the Excited-State Landscape in Iron(II) Chromophores with Protons K. Witas, S. Santosh Nair, T. Maisuradze, L. Zedler, H. Schmidt, P. Garcia-Porta, A. S. J. Rein, S. Rau, S. Kupfer, B. Dietzek-Ivanšić, D. U. Sorsche, J. Am. Chem. Soc. 2024, 146, 19710-19719 |
| 212 | Site-specific electronic structure of covalently linked bimetallic dyads from nitrogen K-edge x-ray absorption spectroscopy E. S. Ryland, X. Liu, G. Kumar, S. L. Raj, Z.-L. Xie, A. K. Mengele, S. S. Fauth, K. Siewerth, B. Dietzek-Ivanšić, S. Rau, K. L. Mulfort, X. Li, A. A. Cordones, J. Chem. Phys. 2024, 160, 084307 |
| 211 | An Algebraic Blueprint for Predicting Turnover Numbers and Endpoints in Photocatalysis S. Klingler, M. Hlavatsch, B. Bagemihl, A. K. Mengele, A.-L. Gaus, M. von Delius, S. Rau, B. Mizaikoff, ChemPhysChem 2024, 25, e202300767 |
| 210 | Poly(dehydroalanine)-Based Hydrogels as Efficient SoftMatter Matrices for Light-Driven Catalysis T. Ceper, M. Langer, N. Vashistha, B. Dietzek-Ivanšić, C. Streb, S. Rau, F. H. Schacher, Macromol. Rapid. Commun. 2024, 2300448 |
2023
| 209 | Prediction of strong solvatochromism in a molecular photocatalyst M. H. Putra, B. Bagemihl, S. Rau, A. Groß, Chem. Eur. J. 2023, 30, e202302643 |
| 208 | A quantum physics layer of epigenetics: a hypothesis deduced from charge transfer and chirality-induced spin selectivity of DNA R. Siebert, O. Ammerpohl, M. Rossini, D. Herb, S. Rau, M. B. Plenio, F. Jelezko, J. Ankerhold, Clin. Epigenetics 2023, 15, 145 |
| 207 | Rationalizing In Situ Active Repair in Hydrogen Evolution Photocatalysis via Non-Invasive Raman Spectroscopy S. Klingler, B. Bagemihl, A. K. Mengele, S. Kaufhold, P. Myllyperkiö, J. Ahokas, M. Pettersson, S. Rau, B. Mizaikoff, Angew. Chem. Int. Ed. 2023, e202306287 |
| 206 | Multiple Triplet Metal-Centered Jahn-Teller Isomers Determine Temperature-Dependent Luminescence Lifetimes in [Ru(bpy)3]2+ D. Hernández-Castillo, R. Nau, M.-A. Schmid, S. Tschierlei, S. Rau, L. González, Angew. Chem. Int. Ed., 2023, 62, e202308803 |
| 205 | Bridging Platinum and Palladium to Bipyridine-Annulated Perylene for Light-Driven Hydrogen Evolution D. Costabel, R. De, F. Jacobi, J. Eichhorn, K. Hotzel, A. Nabiyan, C. Neumann, A. Turchanin, S. Kupfer, F. H. Schacher, S. Rau, B. Dietzek-Ivanšić, K. Peneva, ACS Catal., 2023, 13, 7159-7169 |
| 204 | Block copolymer micelles as efficient colloidal photosensitizers in the light-driven hydrogen evolution reaction J. Eichhorn, P. Hofmann, B. Bagemihl, C. Streb, S. Rau, F. H. Schacher, J. Mater. Chem. A., 2023, 11, 11334-11340 |
| 203 | Gatekeeping Effect of Ancillary Ligand on Electron Transfer in Click Chemistry-Linked Tris-Heteroleptic Ruthenium(II) Donor–Photosensitizer–Acceptor Triads B. Bagemihl, A. Pannwitz, S. Rau, Sol. RRL, 2023, 2201135 |
| 202 | Stability of Catalytic Centres in Light-driven Hydrogen Evolution by Oligonuclear Photocatalysts M. Lämmle, A. K. Mengele, G. E. Shillito, S. Kupfer, S. Rau, Chem. Eur. J., 2023, 29, e2022027 |
| 201 | Red Light Absorption of [ReI(CO)3(α-diimine)Cl] Complexes through Extension of the 4,4′-Bipyrimidine Ligand’s π-System N. Meitinger, S. Mandal, D. Sorsche, A. Pannwitz, S. Rau, Molecules, 2023, 28, 1905 |
| 200 | Learning from Nature’s Example: Repair Strategies in Light-Driven Catalysis A. K. Mengele, S. Rau, JACS Au, 2023, 3, 36-46 |
| 199 | Plugging the 3MC Sink in RuII-Based Photocatalysts G. E. Shillito, S. Rau, S. Kupfer, ChemCatChem, 2023, 15, e202201489 |
2022
| 198 | Supramolecular Aggregation Control in Polyoxometalates Covalently Functionalized with Oligoaromatic Groups S. Knoll, M. Hänle, A. K. Mengele, D. Sorsche, S. Rau, C. Streb, Chem. Eur. J., 2022, 29, e202203469 |
| 197 | A Carbon Nanodot Based Near-Infrared Photosensitizer with a Protein-Ruthenium Shell for Low Power Photodynamic Applications N. Naskar, W. Liu, H. Qi, A. Stumper, S. Fischer, T. Diemant, R. J. Behm, U. Kaiser, S. Rau, T. Weil, S.Chakrabortty, ACS Appl. Mater. Interfaces, 2022, 14, 48327-48340 |
| 196 | Efficient Access of Phenyl-Spaced 5,5′-Bridged Dinuclear Ruthenium Metal Complexes and the Effect of Dynamic Ligand Exchange on Catalysis M. Lämmle, S. Volk, M. Klinkerman, M. Müßler, A. K. Mengele, S. Rau, Photochem, 2022, 2, 831-848 |
| 195 | Insights into the different mechanistic stages of light-induced hydrogen evolution of a 5,5’-bisphenanthroline linked RuPt complex M. Lämmle, T. D. Pilz, R. J. Kutta, M. Müßler, A. K. Mengele, H. Görls, F. W. Heinemann, S. Rau, Dalton. Trans., 2022, 51, 15282-15291 |
| 194 | A Triad Photoanode for Visible Light-Driven Water Oxidation via Immobilization of Molecular Polyoxometalate on Polymeric Carbon Nitride R. Gong, D. Mitoraj, D. Gao, M. Mundszinger, D. Sorsche, U. Kaiser, C. Streb, R. Beranek, S. Rau, Adv. Sustainable Syst., 2022, 6, 2100473 |
| 193 | Photocatalytic Reduction of Nicotinamide Co-factor by Perylene Sensitized RhIII Complexes J. Brückmann, C. Müller, I. Friedländer, A. K. Mengele, K. Peneva, B. Dietzek-Ivanšić, S. Rau, Chem. Eur. J., 2022, e202201931 |
| 192 | Pyrimidoquinazolinophenanthroline Opens Next Chapter in Design of Bridging Ligands for Artificial Photosynthesis J. Brückmann, C. Müller, T. Maisuradze, A. K. Mengele, D. Nauroozi, S. Fauth, A. Gruber, S. Gräfe, K. Leopold, S. Kupfer, B. Dietzek-Ivanšić, S. Rau, Chem. Eur. J., 2022, e202200766 |
| 191 | Evaluation of 1H-NMR Spectroscopy-Based Quantification Methods of the Supramolecular Aggregation of a Molecular Photosensitizer C. Pehlken, M. G. Pfeffer, K. Reich, S. Rau, Photochem. Photobiol., 2022, 98, 1255-1263 |
| 190 | Comparative Evaluation of Light-Driven Catalysis: A Framework for Standardized Reporting of Data D. Ziegenbalg, A. Pannwitz, S. Rau, B. Dietzek-Ivanšić, C. Streb, Angew. Chem. Int. Ed., 2022, e202114106 |
| 189 | Not that innocent – ammonium ions boost homogeneous light-driven hydrogen evolution M. Heiland, R. De, S. Rau, B. Dietzek-Ivanšić, C. Streb, Chem. Commun., 2022, 58, 4603-4606 |
| 188 | Link to glow - iEDDA conjugation of a Ruthenium(II) tetrazine complex leading to dihydropyrazine and pyrazine complexes with improved 1O2 formation ability C. Müller, P. Wintergerst, S. S. Nair, N. Meitinger, S. Rau, B. Dietzek-Ivanšić, J. Photochem. Photobiol., 2022, 11, 100130 |
| 187 | Outpacing conventional nicotinamide hydrogenation catalysis by a strongly communicating heterodinuclear photocatalyst L. Zedler, P. Wintergerst, A. K. Mengele, C. Müller, C. Li, B. Dietzek-Ivanšić, S. Rau, Nat. Commun., 2022, 13, 2538 |
| 186 | Boosting efficiency in light-driven water splitting by dynamic irradiation through synchronizing reaction and transport processes M. Sender, F. L. Huber, M. C. G. Moersch, D. Kowalczyk, J. Hniopek, S. Klingler, M. Schmitt, S. Kaufhold, K. Siewerth, J. Popp, B. Mizaikoff, D. Ziegenbalg, S. Rau, ChemSusChem, 2022, e202200708 |
| 185 | Influence of the linker chemistry on the photoinduced charge-transfer dynamics of heterodinuclear photocatalysts L. Zedler, C. Müller, P. Wintergerst, A. K. Mengele, S. Rau, B. Dietzek-Ivanšić, Chem. Eur. J., 2022, e202200490 |
| 184 | Monosubstitution of 1H-imidazo[4,5-f][1,10]phenanthroline Ligands yields Maximum Luminescence Quantum Yield in Ruthenium Polypyridyl Complexes M. Lämmle, B. Bagemihl, D. Nauroozi, L. Petermann, A. Pannwitz, S. Rau, ChemPhotoChem, 2022, e202200053 |
| 183 | Active repair of a dinuclear photocatalyst for visible-light-driven hydrogen production M. G. Pfeffer, C. Müller, E. T. E. Kastl, A. K. Mengele, B. Bagemihl, S. S. Fauth, J. Habermehl, L. Petermann, M. Wächtler, M. Schulz, D. Chartrand, F. Laverdière, P. Seeber, S. Kupfer, S. Gräfe, G. S. Hanan, J. G. Vos, B. Dietzek-Ivanšić, S. Rau, Nat. Chem., 2022, 14, 500-506 |
| 182 | A photosensitizer–polyoxometalate dyad that enables the decoupling of light and dark reactions for delayed on-demand solar hydrogen production S. Amthor, S. Knoll, M. Heiland, L. Zedler, Ch. Li, D. Nauroozi, W. Tobaschus, A. K. Mengele, M. Anjass, U. S. Schubert, B. Dietzek-Ivanšić, S. Rau, C. Streb, Nat. Chem., 2022, 14, 321-327 |
| 181 | Transforming Escherichia coli Proteomembranes into Artificial Chloroplasts Using Molecular Photocatalysis A. K. Mengele, D. Weixler, S. Amthor, B. J. Eikmanns, G. M. Seibold, S. Rau, Angew. Chem. Int. Ed., 2022, 61, e202114842 |
| 180 | Merging of a perylene moiety enables a Ru(II) photosensitizer with long-lived excited states and the efficient production of singlet oxygen M.-A. Schmid, J. Brückmann, J. Bösking, D. Nauroozi, M. Karnahl, S. Rau, S. Tschierlei, Chem. Eur. J., 2022, 28, e202103609 |
2021
| 179 | Rhodium-Complex-Functionalized and Polydopamine-Coated CdSe@CdS Nanorods for Photocatalytic NAD+ Reduction M. Boecker, M. Micheel, A. K. Mengele, C. Neumann, T. Herberger, T. Marchesi D’Alvise, B. Liu, A. Undisz, S. Rau, A. Turchanin, C. V. Synatschke, M. Wächtler, T. Weil, ACS Appl. Nano Mater., 2021, 4, 12913-12919 |
| 178 | The electron that breaks the catalyst's back - excited state dynamics in intermediates of molecular photocatalysts C. Müller, I. Friedländer, B. Bagemihl, S. Rau, B. Dietzek, Phys. Chem. Chem. Phys., 2021, 23, 27397-27403 |
| 177 | Multifunctional Polyoxometalate Platforms for Supramolecular Light-driven Hydrogen Evolution S. Maloul, M. van den Borg, C. Müller, L. Zedler, A. K. Mengele, D. Gaissmaier, T. Jacob, S. Rau, B. Dietzek, C. Streb, Chem. Eur. J., 2021, 27, 16846-16852 |
| 176 | Cobaloxime complex salts: synthesis, patterning on carbon nanomembranes and heterogeneous hydrogen evolution studies E. Oswald, A.-L. Gaus, J. Kund, M. Küllmer, J. Romer, S. Weizenegger, T. Ullrich, A. K. Mengele, L. Petermann, R. Leiter, P. R. Unwin, U. Kaiser, S. Rau, A. Kahnt, A. Turchanin, M. von Delius, C. Kranz, Chem. Eur. J., 2021, 27, 16896-16903 |
| 175 | Strong ligand stabilization based on π-extension in a series of Ruthenium terpyridine water oxidation catalysts S. Amthor, D. Hernández-Castillo, B. Maryasin, P. Seeber, A. K. Mengele, S. Gräfe, L. González, S. Rau. Chem. Eur. J., 2021, 27, 16871-16878 |
| 174 | A phosphonate substituent in a 1,10-phenanthroline ligand boosts light-driven catalytic water oxidation performance sensitized by Ruthenium chromophores S. Amthor, P. Keil, D. Nauroozi, D. Perleth, S. Rau, Eur. J. Inorg. Chem., 2021, 4790-4798 |
| 173 | Self-Activation of a Polyoxometalate-Derived Composite Electrocatalyst for the Oxygen Evolution Reaction R. Gong, D. Gao, R. Liu, D. Sorsche, J. Biskupek, U. Kaiser, S. Rau, C. Streb, ACS Appl. Energy. Mater., 2021, 4, 12671-12676 |
| 172 | A Molecular Photosensitizer in a Porous Block Copolymer: Matrix-Implications for the Design of Photocatalytically Active Membranes A. Chettri, J.-H. Kruse, K. K. Jha, L. Dröge, I. Romanenko, C. Neumann, S. Kupfer, A. Turchanin, S. Rau, F. H. Schacher, B. Dietzek, Chem. Eur. J., 2021, 27, 17049-17058 |
| 171 | Switching the Mechanism of NADH Photooxidation by Supramolecular Interactions A. K. Mengele, D. Weixler, A. Chettri, M. Maurer, F. L. Huber, G. M. Seibold, B. Dietzek, B. J. Eikmanns, S. Rau, Chem. Eur. J., 2021, 27, 16840-16845 |
| 170 | Prolonged Luminescence Lifetime of a Dual Emissive Ruthenium Dipyridophenazine-Type Complex in Aprotic and Protic Solvent D. Isakov, M.-A. Schmid, D. Nauroozi, S. Rau, S. Tschierlei, Inorg. Chem., 2021, 60, 14002-14010 |
| 169 | Anatase-Wrapped Rutile Nanorods as an Effective Electron Collector in Hybrid Photoanodes for Visible Light-Driven Oxygen Evolution R. Gong, D. Mitoraj. M. Mundszinger, A. K. Mengele, I. Krivtsov, J. Biskupek, U. Kaiser, R. Beranek, S. Rau, Front. Chem., 2021, 9, 709903 |
| 168 | A Ruthenium(II) Water Oxidation Catalyst Containing a pH-Responsive Ligand Framework F. L. Huber, A. M. Wernbacher, D. Perleth, D. Nauroozi, L. González, S. Rau, Inorg. Chem., 2021, 60, 13299-13308 |
| 167 | Red-light sensitized hole-conducting polymer for energy conversion B. Seidler, R. A. Wahyuono, P. Wintergerst, J. Ahner, M. D. Hager, S. Rau, U. S. Schubert, B. Dietzek, Phys. Chem. Chem. Phys., 2021, 23, 18026-18034 |
| 166 | Influence of the Protonation State on the Excited-State Dynamics of Ruthenium(II) Complexes with Imidazole π‑Extended Dipyridophenazine Ligands C. Müller, D. Isakov, S. Rau, B. Dietzek, J. Phys. Chem. A, 2021, 125, 5911-5921 |
| 165 | Localizing the initial excitation – A case study on NiO photocathodes using Ruthenium dipyridophenazine complexes as sensitizers R. A. Wahyuono, M. Braumüller, S. Bold, S. Amthor, D. Nauroozi, J. Plentz, M. Wächtler, S. Rau, B, Dietzek, Spectrochim. Acta A Mol. Biomol. Spectrosc., 2021, 252, 119507 |
| 164 | Pyrimidine-Substituted Hexaarylbenzenes as Versatile Building Blocks for N–Doped Organic Materials N. Meitinger, A. K. Mengele, D. Nauroozi, S. Rau, Org. Mater., 2021, 3, 295-302 |
| 163 | Photocathodes beyond NiO: charge transfer dynamics in a π‑conjugated polymer functionalized with Ru photosensitizers
|
2020
| 162 | Sonochemical Hydrogen Production as a Potential Interference in Light-Driven Hydrogen Evolution Catalysis I. Roger, S. Rau, C. Streb, ACS Omega, 2020, 5, 2150-2153 |
| 161 | Intracellular Photophysics of an Osmium Complex bearing an Oligothiophene Extended Ligand K. R. A. Schneider, A. Chettri, H. D. Cole, K. Reglinski, J. Brückmann, J. A. Roque, A. Stumper, D. Nauroozi, S. Schmid, C. B. Lagerholm, S. Rau, P. Bäuerle, C. Eggeling, C. G. Cameron, S. A. McFarland, B. Dietzek, Chem. Eur. J., 2020, 26, 14844-14851 |
| 160 | Tetraaryl Cyclopentadienones: Experimental and Theoretical Insights into Negative Solvatochromism and Electrochemistry N. Meitinger, A. K. Mengele, K. Witas, S. Kupfer, S. Rau, D. Nauroozi, Eur. J. Org. Chem., 2020, 6555 |
| 159 | Molecular Scylla and Charybdis: Maneuvering between pH Sensitivity and Excited-State Localization in Ruthenium Bi(benz)imidazole Complexes A. K. Mengele, C. Müller, D. Nauroozi, S. Kupfer, B. Dietzek, S. Rau, Inorg. Chem., 2020, 59, 12097–12110 |
| 158 | Electron storage capability and singlet oxygen productivity of a Ru(II) photosensitizer containing a fused naphthaloylenebenzene moiety at the 1,10-phenanthroline ligand Y. Yang, J. Brückmann, W. Frey, S. Rau, M. Karnahl, S. Tschierlei, Chem. Eur. J., 2020, 26, 17027–17034 |
| 157 | Heterojunction of CuO nanoclusters with TiO2 for photo-oxidation of organic compounds and for hydrogen production M. Guadalupe Méndez-Medrano, E. Kowalska, B. Ohtani, D. Bahena Uribe, C. Colbeau-Justin, S. Rau, J. L. Rodriguez-López, H. Remita, J. Chem. Phys., 2020, 153(3), 034705 |
| 156 | Somatostatin receptor mediated targeting of acute myeloid leukemia by photodynamic metal complexes for light induced apoptosis N. M. Vegi, S. Chakrabortty, M. M. Zegota, S. L. Kuan, A. Stumper, V. P. S. Rawat, S. Sieste, C. Buske, S. Rau, T. Weil, M. Feuring-Buske, Scientific Reports, 2020, 10(1), 371 |
| 155 | The Metallic Traveler: Formate- and Photoinduced Regioselective Phenanthroline Deuterations via Reductively Activated RhCp* Centers A. K. Mengele, S. Rau, Organometallics, 2020, 39(14), 2739-2748 |
| 154 | Minimizing Side Product Formation in Alkyne Functionalization of Ruthenium Complexes by Introduction of Protecting Groups P. Wintergerst, K. Witas, D. Nauroozi, M. A. Schmid, E. Dikmen, S. Tschierlei, S. Rau, Zeitschrift für Anorg. und Allg. Chemie, 2020, 646, 842–848 |
| 153 | Structure of Diethyl-Phosphonic Acid Anchoring Group Affects the Charge-Separated State on an Iridium(III) Complex Functionalized NiO Surface R. A. Wahyuono, S. Amthor, C. Müller, S. Rau, B. Dietzek, ChemPhotoChem, 2020, 4, 1-13 |
| 152 | Tailored protective groups for surface immobilization of ruthenium dyes S. Amthor, H. Braun, J. Gröne, D. Nauroozi, T. Jacob and S. Rau, Dalton Trans., 2019, 49, 3735-3742 |
2019
| 151 | Synthesis and hydrogen evolving catalysis of a panchromatic photochemical molecular device J. Habermehl, D. Nauroozi, M. Martynow, Y. E. Vilk, R. Beranek, J. Guthmuller, S. Rau, Sustainable Energy Fuels, 2019, DOI: |
| 150 | Two Emissive Long-Lived Excited States of an Imidazole-Functionalized Ruthenium Dipyridophenazine Complex D. Isakov, R. Giereth, D. Nauroozi, S. Tschierlei, S. Rau, Inorg. Chem. 2019, 58, 12646-12653 |
| 149 | Unraveling the Light-Activated Reaction Mechanism in a Catalytically Competent Key Intermediate of a Multifunctional Molecular Catalyst for Artificial Photosynthesis L. Zedler, A. K. Mengele, K. M. Ziems, Y. Zhang, M. Wächtler, S. Gräfe, T. Pascher, S. Rau, S. Kupfer, B. Dietzek, Angew. Chem. Int. Ed. 2019, 58, 13140-13148 |
| 148 | Stille Expands the Family: Access to 5,6-Bis-2-thienyl-Substituted Phenanthroline Under Mild Conditions for Luminescent Ruthenium Complexes J. Brückmann, A. A. Heidecker, D. Popovic, A. K. Mengele, D. Nauroozi, P. Bäuerle, S. Rau, Eur. J. Inorg. Chem., 2019, 1832–1838 |
| 147 | Impact of Alkyne Functionalization on Photophysical and Electrochemical Properties of 1,10‐Phenanthrolines and Their RuII Complexes P. Wintergerst, A. K. Mengele, D. Nauroozi, S. Tschierlei, S. Rau, Eur. J. Inorg. Chem., 2019, 1988–1992 |
| 146 | Homogeneous visible light-driven hydrogen evolution by the molecular molybdenum sulfide model [Mo2S12]2− A. Rajagopal, F. Venter, T. Jacob, L. Petermann, S. Rau, S. Tschierlei, C. Streb, Sustainable Energy Fuels, 2019, 3, 92-95 |
| 145 | Excited state properties of a series of molecularphotocatalysts investigated by time dependent density functional theory M. Martynow, S. Kupfer, S. Rau, J. Guthmuller, Phys. Chem. Chem. Phys., 2019, 21, 9052-9060 |
2018
| 144 | Photocatalytic Generation of Hydrogen Using Dinuclear π-Extended Porphyrin-Platinum Compounds P. Lang, J. Habermehl, S. I. Troyanov, S. Rau, M. Schwalbe, Chem. Eur. J., 2018, 24(13), 3225-3233 |
| 143 | Multi-phase real-time monitoring of oxygen evolution enables in operando water oxidation catalysis studies F. L. Huber, S. Amthor, B. Schwarz, B. Mizaikoff, C. Streb, S. Rau, Sustain. Energy Fuels, 2018, 2, 1974-1978 |
| 142 | One Scaffold, Many Possibilities: CuAAC, SPAAC and Maleimide-Thiol Coupling of Ruthenium(II) Polypyridyl Complexes A. Stumper, M. Lämmle, A. K. Mengele, D. Sorsche, S. Rau, Eur. J. Inorg. Chem., 2018, 586-596 |
2017
| 141 | Rational in situ tuning of a supramolecular photocatalyst for hydrogen evolution S. Kaufhold, D. Imanbaew, C. Riehn, S. Rau, Sustainable Energy Fuels, 2017, 1, 2066-2070 |
| 140 | Experimental and Theoretical Investigation into the Light-Driven Hydrogen Evolution by Polyoxometalate-Photosensitizer Dyads S. Schönweiz, M. Heiland, M. Anjass, T. Jacob, S. Rau, C. Streb, Chem. Eur. J., 2017, 23, 15370-15376 |
| 139 | Structural and reactivity insights into covalently linked Cu(I) complex-Anderson polyoxometalates S. Schönweiz, D. Sorsche, B. Schwarz, S. Rau, C. Streb, Dalton Trans., 2017, 46(30), 9760-9764 |
| 138 | Coupling Molecular Photocatalysis to Enzymatic Conversion A. K. Mengele, G. M. Seibold, B. J. Eikmanns, S. Rau, ChemCatChem, 2017, 9, 4369-4376 |
| 137 | Efficient Access to 5- and 5,6-Dibromophenanthroline Ligands A. Stumper, T. D. Pilz, M. Schaub, H. Görls, D. Sorsche, K. Peuntinger, D. Guldi, S. Rau, Eur. J. Inorg. Chem., 2017, 3799-3810 |
| 136 | Synthesis and characterization of a ruthenium(II) complex for the development of supramolecular photocatalysts containing multidentate coordination spheres F. L. Huber, D. Nauroozi, A. K. Mengele, S. Rau, Eur. J. Inorg. Chem., 2017, 4020-4027 |
| 135 | Product Selectivity in Homogeneous Artificial Photosynthesis Using [(bpy)Rh(Cp*)X]n+-Based Catalysts A. K. Mengele, S. Rau, Inorganics, 2017, 5(2), 35 |
| 134 | Optical sensing of anions via supramolecular recognition with biimidazole complexes S. A. Rommel, D. Sorsche, M. Fleischmann, S. Rau, Chem. Eur. J., 2017, 23, 18101-18119 |
| 133 | Pump-Probe Fragmentation Action Spectroscopy: A Powerful Tool to Unravel Light-Induced Processes in Molecular Photocatalysts D. Imanbaew, J. Lang, M. F. Gelin, S. Kaufhold, M. G. Pfeffer, S. Rau, C. Riehn, Angew. Chem. Int. Ed., 2017, 56(20), 5471-5474 |
| 132 | "Trojan horse" effect in photocatalysis-how anionic silver impurities influence apparent catalytic activity S. Kaufhold, L. Petermann, D. Sorsche, S. Rau, Chem. Eur. J., 2017, 23(10), 2271-2274 |
| 131 | Mitochondria Targeted Protein-Ruthenium Photosensitizer for Efficient Photodynamic Applications S. Chakrabortty, B. K. Agrawalla, A. Stumper, N. M. Vegi, S. Fischer, C. Reichardt, M. Koegler, B. Dietzek, M. Feuring-Buske, C. Buske, S. Rau, T. Weil, J. Am. Chem. Soc., 2017, 139(6), 2512-2519 |
2016
| 130 | Surface Modification of TiO2 with Au Nanoclusters for Efficient Water Treatment and Hydrogen Generation Under Visible Light M. G. Mendez Medrano, E. K. Kowalska, A. Lehoux, A. Herissan, B. Ohtani, S. Rau, C. Colbeau-Justin, J. L. L. Rodriguez Lopez, H. Remita, J. Phys. Chem. C, 2016, 120(43), 25010-25022 | |
| 129 | CLICK 'n' Sleep: Light-Switch Behavior of Triazole-Containing Tris(bipyridyl)ruthenium Complexes M. Braumüller, M. Staniszewska, J. Guthmuller, S. Rau, Eur. J. Inorg. Chem., 2016, 2016(31), 4958-4963 | |
| 128 | "CLICKable" azide-functionalized phosphonates for the surface-modification of molecular and solid-state metal oxides S. Schönweiz, S. Knoll, M. Braumüller, M. Anjass, S. Rau, C. Streb, Dalton Trans., 2016, 45, 16121-16124 | |
| 127 | ∏-Stacking attraction vs. electrostatic repulsion: competing supramolecular interactions in a tpphz-bridged Ru(II)/Au(III) complex D. Sorsche, M. Schaub, F. W. Heinemann, J. Habermehl, S. Kuhri, D. Guldi, J. Guthmuller, S. Rau, Dalton Trans., 2016, 45(32), 12846-12853 | |
| 126 | Covalent Photosensitizer-Polyoxometalate-Catalyst Dyads for Visible-Light-Driven Hydrogen Evolution S. Schönweiz, S. A. Rommel, J. Kübel, M. Micheel, B. Dietzek, S. Rau, C. Streb, Chem.-Eur. J., 2016, 22(34), 12002-12005 | |
| 125 | Peripheral ligands as electron storage reservoirs and their role in enhancement of photocatalytic hydrogen generation Q. Pan, L. Freitag, T. Kowacs, J. C. Falgenhauer, J. P. Korterik, D. Schlettwein, W. R. Browne, M. T. Pryce, S. Rau, L. Gonzalez, J. G. Vos, A. Huijser, Chem. Comm., 2016, 52(60), 9371-9374 | |
| 124 | Making Use of Obstacles: Alternative Synthetic Approaches towards Osmium(II)-Based Photochemical Molecular Devices J. Habermehl, D. Sorsche, P. Murszat, S. Rau, Eur. J. Inorg. Chem., 2016, 21, 3423-3428 | |
| 123 | Oxygen-Dependent Photocatalytic Water Reduction with a Ruthenium(imidazolium) Chromophore and a Cobaloxime Catalyst L. Petermann, R. Staehle, M. Pfeifer, C. Reichardt, D. Sorsche, M. Wächtler, J. Popp, B. Dietzek, S. Rau, Chem. Eur. J., 2016, 22(24), 8240-8253 | |
| 122 | Synthesis and characterization of ruthenium and rhenium dyes with phosphonate anchoring groups M. Braumüller, M. Schulz, M. Staniszewska, D. Sorsche, M. Wunderlin, J. Popp, J. Guthmuller, B. Dietzek, S. Rau, Dalton Trans., 2016, 45(22), 9216-9228 | |
| 121 | Visible-light sensitized photocatalytic hydrogen generation using a dual emissive heterodinuclear cyclometalated iridium(III)/ruthenium(II) complex S. A. Rommel, D. Sorsche, S. Schönweiz, J. Kübel, N. Rockstroh, B. Dietzek, C. Streb, S. Rau, J. Organomet. Chem., 2016, 821, 163-170. | |
| 120 | Functional Dimming of Pincer-Shaped Bibenzimidazole-Ruthenium(II) Complexes with Improved Anion-Sensitive Luminescence D. Sorsche, S. A. Rommel, S. Rau, Eur. J. Inorg. Chem., 2016, 10, 1503-1513 | |
| 119 | Generation of a stable supramolecular hydrogen evolving photocatalyst by alteration of the catalytic center A. K. Mengele, S. Kaufhold, C. Streb, S. Rau, Dalton Trans., 2016, 45(15), 6612-6618 | |
| 118 | Subtle Changes to Peripheral Ligands Enable High Turnover Numbers for Photocatalytic Hydrogen Generation with Supramolecular Photocatalysts T. Kowacs, L. O'Reilly, Q. Pan, A. Huijser, P. Lang, S. Rau, W. R. Browne, M. T. Pryce, J. G. Vos, Inorg. Chem., 2016, 55(6), 2685-2690 | |
| 117 | Detecting and Preventing the Formation of Photosensitizer-Catalyst Colloids in Homogeneous Light-Driven Water Oxidation B. Kirchhoff, S. Rau, C. Streb, Eur. J. Inorg. Chem., 2016, 9, 1425-1429 | |
| 116 | CuAAC click reactions for the design of multifunctional luminescent ruthenium complexes N. Zabarska, A. Stumper, S. Rau, Dalton Trans., 2016, 45(6), 2338-2351 | |
| 115 | Titania modification with a ruthenium(II)complex and gold nanoparticles for photocatalytic degradation of organic compounds S. Zheng, Z. Wei, K. Yoshiiri, M. Braumüller, B. Ohtani, S. Rau, E. Kowalska, Photochem. Photobiol. Sci., 2016, 15(1), 69-79 | |
| 114 | Interaction of an iridium(III)-bibenzimidazole complex with anions - implications for luminescent sensing S. A. Rommel, D. Sorsche, A. Dixit, S. Rau, Eur. J. Inorg. Chem., 2016, 1, 40-48 | |
| 113 | A supramolecular H-bond driven light switch sensor for small anions S. A. Rommel, D. Sorsche, S. Rau, Dalton Trans., 2016, 45(1), 74-77 |
2015
| 112 | A new method for the utilization of compounds of the type [Ru(bpy)2(CO)Cl]+ as a starting material for the synthesis of [Ru(N6)]2+ type compounds N. Zabarska, J. G. Vos, S. Rau, Polyhedron, 2015, 102, 173-175 | |
| 111 | Towards Ruthenium-Based Building Blocks for CuAAC Click Reactions: Challenges in Generating Ruthenium(II) Polypyridine Alkynes N. Zabarska, D. Sorsche, F. W. Heinemann, S. Glump, S. Rau, Eur. J. Inorg. Chem., 2015, 29, 4869-4877 | |
| 110 | Hybrid photocatalysts composed of titania modified with plasmonic nanoparticles and ruthenium complexes for decomposition of organic compounds E. Kowalska, K. Yoshiiri, Z. Wei, S. Zheng, E. Kastl, H. Remita, B. Ohtani, S. Rau, Appl. Catal. B-Environ., 2015, 178, 133-143 | |
| 109 | In situ spectroelectrochemical and theoretical study on the oxidation of a 4H-imidazole-ruthenium dye adsorbed on nanocrystalline TiO2 thin film electrodes Y. Zhang, S. Kupfer, L. Zedler, J. Schindler, T. Bocklitz, J. Guthmuller, S. Rau, B. Dietzek, PhysChemChemPhys, 2015, 17(44), 29637-46 | |
| 108 | Supramolecular bimetallic assemblies for photocatalytic hydrogen generation from water T. Kowacs, Q. Pan, P. Lang, L. O'Reilly, S. Rau, W. R. Browne, M. T. Pryce, A. Huijser, J. G. Vos, Faraday Discuss., 2015, 185, 143-170 | |
| 107 | Modular Synthesis of Elongated Phosphonate Bipyridines M. Braumüller, D. Sorsche, M. Wunderlin, S. Rau, Eur. J. Org. Chem., 2015, 27, 5987-5994 | |
| 106 | Novel phenanthroline-diaryldiazadiene ligands with heteroditopic coordination spheres D. Sorsche, C. Pehlken, C. Baur, S. Rommel, K. Kastner, C. Streb, S. Rau, Dalton Trans., 2015, 44(35), 15404-15407 | |
| 105 | Ruthenium Imidazophenanthrolinium Complexes with Prolonged Excited-State Lifetimes R. Staehle, C. Reichardt, J. Popp, D. Sorsche, L. Petermann, K. Kastner, C. Streb, B. Dietzek, S. Rau, Eur. J. Inorg. Chem., 2015, 23, 3932-3939 | |
| 104 | Protonation-Dependent Luminescence of an Iridium(III) Bibenzimidazole Chromophone S. A. Rommel, D. Sorsche, N. Rockstroh, F. W. Heinemann, J. Kuebel, M. Waechtler, B. Dietzek, S. Rau, Eur. J. Inorg. Chem., 2015, 22, 3730-3739 | |
| 103 | Receptor selective ruthenium-somatostatin photosensitizer for cancer targeted photodynamic applications T. Wang, N. Zabarska, Y. Wu, M. Lamla, S. Fischer, K. Monczak, D. Y. W. Ng, S. Rau, T. Weil, Chem. Comm., 2015, 51(63), 12552-12555 | |
| 102 | How Does Peripheral Functionalization of Ruthenium(II)_Terpyridine Complexes Affect Spatial Charge Redistribution after Photoexcitation at the Franck-Condon Point? J. Preiss, M. Jaeger, S. Rau, B. Dietzek, J. Popp, T. Martinez, M. Presselt, ChemPhysChem, 2015, 16(7), 1395-1404 | |
| 101 | Optimization of Hydrogen-Evolving Photochemical Molecular Devices M. G. Pfeffer, T. Kowacs, M. Wächtler, J. Guthmuller, B. Dietzek, J. G. Vos, S. Rau, Angew. Chem. Int. Ed, 2015, 54(22), 6627-6631 | |
| 100 | Optimized synthesis of tert.-butyl-phenyl-substituted tetrapyridophenazine ligand and its Ru(II)complexes and determination of dimerization behaviour of the complexes through supramolecular "Fingerhakel" K. Ritter, C. Pehlken, D. Sorsche, S. Rau, Dalton Trans., 2015, 44, 8889-8905 | |
| 99 | Synthesis and characterization of an immobilizable photochemical molecular device for H2-generation M. Braumüller, M. Schulz, D. Sorsche, M. G. Pfeffer, M. Schaub, J. Popp, B.-W. Park, A. Hagfeldt, B. Dietzek, S. Rau, Dalton Trans., 2015, 44(12), 5577-86 | |
| 98 | Transition metal complexes with N-heterocyclic carbene ligands: From organometallic hydrogenation reactions toward water splitting S. Kaufhold, L. Petermann, R. Staehle, S. Rau, Coord. Chem. Rev., 2015, 304, 73-87 | |
| 97 | Synthetic Strategies for Variably Substituted Ruthenium-Imidazophenanthrolinium Complexes L. Petermann, R. Staehle, T. D. Pilz, D. Sorsche, H. Goerls, S. Rau, Eur. J. Inorg. Chem., 2015, 5, 750-762 | |
| 96 | Towards Hydrogen Evolution Initiated by LED Light: 2-(1H-1,2,3-Triazol-4-yl)pyridine-Containing Polymers as Photocatalyst B. Happ, J. Kuebel, M. G. Pfeffer, A. Winter, M. D. Hager, B. Dietzek, S. Rau, U. S. Schubert, Macromol. Rapid Comm., 2015, 671-677 | |
| 95 | Photophysics of a Ruthenium 4H-Imidazole Panchromatic Dye in Interaction with Titanium Dioxide J. Schindler, S. Kupfer, M. Wächtler, J. Guthmuller, S. Rau, B. Dietzek, ChemPhysChem, 2015, 16(5), 1061-1070 | |
| 94 | Ultrafast Intramolecular Relaxation and Wave-Packet Motion in a Ruthenium-Based Supramolecular Photocatalyst M. Wächtler, J. Guthmuller, S. Kupfer, M. Maiuri, D. Brida, J. Popp, S. Rau, G. Cerullo, B. Dietzek, Chem. Eur. J., 2015, 7668-7674 | |
| 93 | Palladium versus Platinum: The Metal in the Catalytic Center of a Molecular Photocatalyst Determines the Mechanism of the Hydrogen Production with Visible Light M. G. Pfeffer, B. Schäfer, G. Smolentsev, J. Uhlig, E. Nazarenko, J. Guthmuller, C. Kuhnt, M. Wächtler, B. Dietzek, V. Sundström, S. Rau, Angew. Chem. Int. Ed., 2015, 54(17), 5044-5048 | |
| 92 | Cluster-controlled dimerisation in supramolecular ruthenium photosensitizer-polyoxometalate systems K. Heussner, K. Peuntinger, N. Rockstroh, S. Rau, C. Streb, Dalton Trans., 2015, 44(1), 330-337 |
2014
| 91 | Synthesis and Characterization of a Trisheteroleptic Ru (II)-Based Molecular Switch K. Monczak, K. Peuntinger, D. Sorsche, F. W. Heinemann, D. M. Guldi, S. Rau, Chem. Eur. J., 2014, 20(47), 15426-15433 | |
| 90 | Carbene based photochemical molecular assemblies for solar driven hydrogen generation K. Peuntinger, T. D. Pilz, R. Staehle, M. Schaub, S. Kaufhold, L. Petermann, M. Wunderlin, H. Goerls, F. W. Heinemann, J. Li, T. Drewello, J. G. Vos, D. M. Guldi, S. Rau, Dalton Trans., 2014, 43(36), 13683-13695 | |
| 89 | Photocatalytic Generation of Hydrogen from Water under Aerobic Conditions R. Staehle, S. Losse, M. R. Filipovic, I. Ivanovic-Burmazovic, J. G. Vos, S. Rau, ChemPlusChem, 2014, 79(11), 1614-1621 | |
| 88 | Supramolecular activation of a molecular photocatalyst M. G. Pfeffer, C. Pehlken, R. Staehle, D. Sorsche, C. Streb, S. Rau, Dalton Trans., 2014, 43, 13307-13315 | |
| 87 | Tuning of photocatalytic activity by creating a tridentate coordination sphere for palladium M. G. Pfeffer, L. Zedler, S. Kupfer, M. Paul, M. Schwalbe, K. Peuntinger, D. M. Guldi, J. Guthmuller, J. Popp, S. Graefe, B. Dietzek, S. Rau, Dalton Trans., 2014, 43(30), 11676-11686 | |
| 86 | A Macrocyclic 2,2'-Bibenzimidazole Ruthenium(II) Chromophore as a Versatile Building Block for Supramolecular Devices D. Sorsche, S. Rau, Eur. J. Inorg. Chem., 2014, 26, 4244-4249 | |
| 85 | Modified bibenzimidazole ligands as spectator ligands in photoactive molecular functional Ru-polypyridine units? Implications from spectroscopy J. Meyer-Ilse, S. Bauroth, M. Bräutigam, M. Schmitt, J. Popp, R. Beckert, N. Rockstroh, T. D. Pilz, K. Monczak, F. W. Heinemann, S. Rau, B. Dietzek, Dalton Trans., 2014, 43(47), 17659-17665 | |
| 84 | A Luminescent Ruthenium Azide Complex as a Substrate for Copper -Catalyzed Click Reactions A. Kroll, K. Monczak, D. Sorsche, S. Rau, Eur. J. Inorg. Chem., 2014, 22, 3462-3466 | |
| 83 | Resonance-Raman spectro-electrochemistry of intermediates in molecular artificial photosynthesis of bimetallic complexes L. Zedler, J. Guthmuller, I. Rabelo de Moraes, S. Kupfer, S. Krieck, M. Schmitt, J. Popp, S. Rau, B. Dietzek, Chem. Comm., 2014, 50(40), 5227-5229 | |
| 82 | An improved synthesis of 4-cyano-1,10-phenanthroline, 4,7-dicyano-1,10-phenanthroline and their bis(4,4'-di-tertbutyl-2,2'-bipyridine)ruthenium(II) complexes R. Staehle, R. Menzel, K. Peuntinger, T. D. Pilz, F. W. Heinemann, D. M. Guldi, R. Beckert, S. Rau, Polyhedron, 2014, 73, 30-36 | |
| 81 | Light-harvesting of polymerizable 4-hydroxy-1,3-thiazole monomers by energy transfer toward photoactive Os(ii) metal complexes in linear polymers A. M. Breul, I. Rabelo de Moraes, R. Menzel, M. Pfeffer, A. Winter, M. D. Hager, S. Rau, B. Dietzek, R. Beckert, U. S. Schubert, Polym. Chem., 2014, 5(8), 2715-2724 | |
| 80 | Trapped in Imidazole: How to Accumulate Multiple Photoelectrons on a Black -Absorbing Ruthenium Complex L. Zedler, S. Kupfer, I. Rabelo de Moraes, M. Waechtler, R. Beckert, M. Schmitt, J. Popp, S. Rau, B. Dietzek, Chem. Eur. J., 2014, 20(13), 3793-3799 | |
| 79 | Water Oxidation Catalyzed by Mononuclear Ruthenium Complexes with a 2,2'-Bipyridine-6,6'dicarboxylate (bda) Ligand: How Ligand Environment Influences the Catalytic Behavior R. Staehle, L. Tong, L. Wang, L. Duan, A. Fischer, M. S. G. Ahlquist, L. Sun, S. Rau, Inorg. Chem., 2014, 53(3), 1307-1319 |
2013
| 78 | Recent progress in the development of bimetallic photocatalysts for hydrogen generation Y. Halpin, M. T. Pryce, S. Rau, D. Dini, J. G. Vos, Dalton Trans., 2013, 42(46), 16243-16254 | |
| 77 | Utilizing Ancillary Ligands to Optimize the Photophysical Properties of 4H-Imidazole Ruthenium Dyes M. Waechtler, M. Maiuri, D. Brida, J. Popp, S. Rau, G. Cerullo, B. Dietzek, ChemPhysChem, 2013, 14(13), 2973-2983 |
2012
| 76 | Structural control of photoinduced dynamics in 4H-imidazole-ruthenium dyes M. Waechtler, S. Kupfer, J. Guthmuller, S. Rau, L. Gonzalez, B. Dietzek, J. Phys. Chem. C, 2012, 116(49), 25664-25676 | |
| 75 | The role of bridging ligand in hydrogen generation by photocatalytic Ru/Pd assemblies G. Singh Bindra, M. Schulz, A. Paul, R. Groarke, S. Soman, J. L. Inglis, W. R. Browne, M. G. Pfeffer, S. Rau, B. J. MacLean, M. T. Pryce, J. G. Vos, Dalton Trans., 2012, 41(42), 13050-13059 | |
| 74 | Plasmonic titania photocatalysts active under UV and visible-light irradiation: influence of gold amount, size and shape E. Kowalska, S. Rau, B. Ohtani, J. Nanotechnology, 2012, 361853, 11 | |
| 73 | A suprising formation of novel bridged bis-benzimidazoles by oxidation of diaminoquinoxalines J. Pressler, R. Beckert, S. Rau, R. Menzel, E. Brickner, W. Guenther, H. Goerls, Z. Naturforsch. B, 2012, 67(4), 367-372 | |
| 72 | Ruthenium dye functionalized gold nanoparticles and their spectral responses L. Zedler, F. Theil, A. Csáki, W. Fritzsche, S. Rau, M. Schmitt, J. Popp, B. Dietzek, RSC Adv., 2012, 2(10), 4463-4471 | |
| 71 | Therapeutic potential of photochemically active metal complexes based on interaction with enzymes S. Rau, S. Zheng, Curr. Top. Med. Chem., 2012, 12(3), 197-209 | |
| 70 | Synthesis and photophysics of a novel photocatalyst for hydrogen production based on a tetrapyridoacridine bridging ligand M. Karnahl, C. Kuhnt, F. W. Heinemann, M. Schmitt, S. Rau, J. Popp, B. Dietzek, Chem. Phys., 2012, 393(1), 65-73 | |
| 69 | Photophysical Dynamics of a Ruthenium Polypyridine Dye Controlled by Solvent pH M. Braeutigam, M. Waechtler, S. Rau, J. Popp, B. Dietzek, J. Phys. Chem. C, 2012, 116(1), 1274-1281 | |
2011
| 68 | Reinvestigating 2,5-di(pyridin-2-yl)pyrazine ruthenium complexes: selective deuteration and Raman spectroscopy as tools to probe ground and excited-state electronic structure in homo- and heterobimetallic complexes M. Schulz, J. Hirschmann, A. Draksharapu, G. Singh Bindra, S. Soman, A. Paul, R. Groarke, M. T. Pryce, S. Rau, W. R. Browne, J. G. Vos, Dalton Trans., 2011, 40(40), 10545-10552 |
| 67 | Tuning of photocatalytic hydrogen production and photoinduced intramolecular electron transfer rates by regioselective bridging ligand substitution M. Karnahl, C. Kuhnt, F. Ma, A. Yartsev, M. Schmitt, B. Dietzek, S. Rau, J. Popp, ChemPhysChem, 2011, 12(11), 2101-2109 |
| 66 | Excited-state annihilation in a homodinuclear ruthenium complex C. Kuhnt, M. Karnahl. M. Schmitt, S. Rau, B. Dietzek, J. Popp, Chem. Comm., 2011, 47(13), 3820-3821 |
| 65 | Excited-state Dynamics in Ruthenium(II)=polypyridine Based Black Absorbers and White Emitters B. Dietzek, R. Siebert, M. Wachtler, M. Schmitt, S. Rau, L. González, U. S. Schubert, J. Popp, Polymer Prep., 2011, 52(2), 883 |
| 64 | Inorganic chemistry 2010. Coordination chemistry R. Wolf, S. Rau, Nach. a.d. Chem., 2011, 59(3), 237-242 |
| 63 | Inorganic chemistry 2010. Main group elements R. C. Fischer, J. J. Weigand, R. Wolf, S. Rau, U. Schatzschneider, Nach. a. d. Chem., 2011, 59(3), 221-236 |
| 62 | Protonation effects on the resonance Raman properties of a novel (terpyridine)Ru(4H-imidazole) complex: an experimental and theoretical case study S. Kupfer, J. Guthmuller, M. Waechtler, S. Losse, S. Rau, B. Dietzek, J. Popp, L. Gonzalez, PhysChemChemPhys, 2011, 13(34), 15580-15588 |
| 61 | Solution and solid-state interactions in a supramolecular ruthenium photosensitizer-polyoxometalate aggregate K. Heussner, K. Peuntinger, N. Rockstroh, L. C. Nye, I. Ivanovic-Burmazovic, S. Rau, C. Streb, Chem. Comm., 2011, 47(24), 6852-6854 |
| 60 | The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts G. Singh Bindra, M. Schulz, A. Paul, S. Soman, R. Groarke, J. Inglis, M. T. Pryce, W. R. Browne, S. Rau, B. J. Maclean, J. G. Vos, Dalton Trans., 2011, 40(41), 10812-10814 |
| 59 | The impact of bromine substitution on the photophysical properties of a homodinuclear Ru-tpphz-Ru complex C. Kuhnt, M. Karnahl, S. Rau, M. Schmitt, B. Dietzek, J. Popp, Chem. Phys. Lett., 2011, 516(1-3), 45-50 |
2010
| 58 | Photoreactors for wastewater treatment: a review E. Kowalska, S. Rau, Recent Patents on Engineering, 2010, 4(3), 242-266 | |
| 57 | Catalytic hydrogen production at cobalt centres S. Losse, J. G. Vos, S. Rau, Coord. Chem. Rev., 2010, 254(21-22), 2492–2504 | |
| 56 | A Concept to Tailor Electron Delocalization: Applying QTAIM Analysis to Phenyl−Terpyridine Compounds M. Presselt, B. Dietzek, M. Schmitt, S. Rau, A. Winter, M. Jäger, U. S. Schubert, J. Popp, J. Phys. Chem. A, 2010, 114, 13163–13174 | |
| 55 | Trendberichte Koordinationschemie S. Rau, Nach. a. d. Chem., 2010, 58(3), 253-256 | |
| 54 | Structural Properties of Ruthenium Biimidazole Complexes Determining the Stability of their Supramolecular Aggregates N. Rockstroh, K. Peuntinger, H. Görls, D. M. Guldi, F. W. Heinemann, B. Schäfer, S. Rau; Z. Naturforsch., 2010, 65(3), 281–290, Widmungsband für F. Saalfrank | |
| 53 | Synthesis and characterisation of heterooligonuclear ruthenium complexes with tri(phenanthrolino)hexaazatriphenylene ligands T. D. Pilz, N. Rockstroh, S. Rau, J. Coord. Chem., 2010, 63(14-16), 2727—2742, Widmungsband für R. van Eldik | |
| 52 | Photochemical Fate: The First Step Determines Efficiency of H2 Formation with a Supramolecular Photocatalyst S. Tschierlei, M. Karnahl, M. Presselt, B. Dietzek, J. Guthmuller, L. Gonzalez, M. Schmitt, S. Rau, J. Popp, Angew. Chem. Int. Ed., 2010, 49(23), 3981-3984 | |
| 51 | Inorganic chemistry 2009 T. Baumgartner, R. Pietschnig, U. Schatzschneider, S. Rau, Nach. a. d. Chem., 2010, 58(3), 239-256 | |
| 50 | The switch that wouldn´t switch - unexpected luminescence from a ruthenium(II)-dppz-complex in water M. Schwalbe, M. Karnahl, S. Tschierlei, U. Uhlemann, M. Schmitt, B. Dietzek, J. Popp, R. Groake, J. G. Vos, S. Rau, Dalton Trans., 2010, 39, 2768-2771 | |
| 49 | Sugar-Selective Enrichment of a D-Glucose-Substituted Ruthenium Bipyridyl Complex Inside HepG2 Cancer Cells M. Gottschaldt, U. S. Schubert, S. Rau, S. Yano, J. G. Vos, T. Kroll, J. Clement, I. Hilger, ChemBioChem, 2010, 11, 649–652 | |
| 48 | Synthesis and characterization of regioselective substituted tetrapyridophenazine ligands and their Ru(II) c omplexes M. Karnahl, S. Tschierlei, C. Kuhnt, B. Dietzek, M. Schmitt, J. Popp, M. Schwalbe, S. Krieck, H. Görls, F. W. Heinemann S. Rau, Dalton Trans., 2010, 39(9), 2359-2370 | |
| 47 | Investigation of substitution effects on novel Ru-dppz complexes by Raman spectroscopy in combination with DFT methods C. Kuhnt, S. Tschierlei, M. Karnahl, S. Rau, B. Dietzek, M. Schmitt, J. Popp, J. Raman Spectrosc., 2010, 41(9), 922-932 | |
| 46 | Substitution-controlled ultrafast excited-state processes in Ru-dppz-derivatives C. Kuhnt, M. Karnahl, S. Tschierlei, K. Griebenow, M. Schmitt, B. Schäfer, S. Krieck, H. Görls, S. Rau, B. Dietzek, J. Popp, PhysChemChemPhys, 2010, 12, 1357-1368 | |
2009
| 45 | Ruthenium polypyridine complexes of tris-(2-pyridyl)-1,3,5-triazine-unusual building blocks for the synthesis of photochemical molecular devices M. Schwalbe, M. Karnahl, H. Görls, D. Chartrand, F. Laverdiere, G. S. Hanan, S. Tschierlei, B. Dietzek, M. Schmitt, J. Popp, J. G. Vos, S. Rau, Dalton Trans., 2009, 20, 4012-4022 | |
| 44 | Synthesis and Photophysical Properties of 3,8-Disubstituted 1,10-Phenanthrolines and Their Ruthenium(II) Complexes M. Karnahl, S. Krieck, H. Görls, S. Tschierlei, M. Schmitt, J. Popp, D. Chartrand, G. S. Hanan, R. Groarke, J. G. Vos, S. Rau, Eur. J. Inorg. Chem., 2009, 33, 4962-4971 | |
| 43 | Resonance Raman Studies of Bis(terpyridine)ruthenium(II) Amino Acid Esters and Diesters K. Heinze, K. Hempel, S. Tschierlei, M. Schmitt, J. Popp, S. Rau, Eur. J. Inorg. Chem., 2009, 21, 3119-3126 | |
| 42 | Photophysics of the Intramolecular Hydrogen-Evolving Ru-Pd Photocatalyst S. Tschierlei, M. Presselt, C. Kuhnt, A. Yartsev, T. Pascher, V. Sundström, M. Karnahl, M. Schwalbe, B. Schäfer, S. Rau, M. Schmitt, B. Dietzek, J. Popp, Chem. Eur. J., 2009, 15(31), 7678-7688 | |
| 41 | Trendberichte Koordinationschemie S. Rau, Nach. a. d. Chem., 2009, 57(3), 231-235 | |
| 40 | Synthesis of Ligands Based on 4H-Imidazoles and Pyridine Subunits: Selective Complexation and Bathochromically Absorbing Complexes J. Blumhoff, R. Beckert, S. Rau, S. Losse, M. Matschke, W. Günther, H. Görls, Eur. J. Inorg. Chem., 2009, 14, 2162-2169 | |
2008
| 39 | Resonance Raman studies of photochemical molecular devices for multielectron storage S. Tschierlei, B. Dietzek, M. Karnahl, S. Rau, F. M. MacDonnell, M. Schmitt, J. Popp, J. Raman Spectrosc., 2008, 39, 557-559 DOI: |
| 38 | Trendberichte Koordinationschemie K. Heinze, S. Rau, Nach. a. d. Chem., 2008, 249-253 |
| 37 | One-Step Synthesis of 4,4′-Dicyano-2,2′-bipyridine and Its Bis(4,4′-di-tert-butyl-2,2′-bipyridine)ruthenium(II) Complex S. Losse, H. Görls, R. Groarke, J. G. Vos, S. Rau, Eur. J. Inorg. Chem., 2008, 28, 4448-4452 |
| 36 | Synthesis and Characterisation of Poly(bipyridine)ruthenium Complexes as Building Blocks for Heterosupramolecular Arrays M. Schwalbe, B. Schäfer, H. Görls, S. Rau, S. Tschierlei, M. Schmitt, J. Popp, G. Vaughan, W. Henry, J. G. Vos, Eur. J. Inorg. Chem., 2008, 21, 3310-3319 |
| 35 | Photoinduced Ligand Transformation in a Ruthenium Polypyridophenazine Complex S. Rau, M. Schwalbe, S. Losse, H. Görls, C. McAlister, F. M. MacDonnell, J. G. Vos, Eur. J. Inorg. Chem., 2008, 7, 1031-1034 |
2007
| 34 | Synthesis and Structure of Novel Sugar-Substituted Bipyridine Complexes of Rhenium and 99m-Technetium M. Gottschaldt, D. Koth, D. Müller, I. Klette, S. Rau, H. Görls, B. Schäfer, R. P. Baum, S. Yano, Chem. Eur. J., 2007, 13(36), 10273–10280 | |
| 33 | Zuckerhaltige Metallkomplexe und deren Verwendung M. Gottschaldt, S. Rau, T. Kroll, J. Clement, Anmeldung Deutsches Patent und Markenamt, 2007, DE102007 032 799.6 | |
| 32 | Heterooligonucleare Verbindungen zur Verwendung als hochaktive Photokatalysatoren sowie Verfahren zu ihrer Herstellung S. Rau, M. Auth, Anmeldung Deutsches Patent und Markenamt, 2007, DE102007 025 424.7 | |
| 31 | Wasserstoff durch mehrkernige Metallkomplex S. Rau, M. Schwalbe, M. Schmitt, J. Popp, Nach. a. d. Chem., 2007, 55(10), 970-974 | |
| 30 | The First Photoexcitation Step of Ruthenium-Based Models for Artificial Photosynthesis Highlighted by Resonance Raman Spectroscopy C. Herrmann, J. Neugebauer, M. Presselt, U. Uhlemann, M. Schmitt, S. Rau, J. Popp, M. Reiher, J. Phys. Chem. B, 2007, 111(21), 6078-6087 | |
| 29 | Ruthenium Complex Fragments as Constituents of Trinuclear Photoactive Supramolecular Assemblies Based on Hydrogen Bond Association K. Halbauer, A. Göbel, A. Sterzik, H. Görls, S. Rau, W. Imhof, Eur. J. Inorg. Chem., 2007, (11), 1508-1514 | |
| 28 | Synthesis and Properties of Tetrasubstituted 1,10-Phenanthrolines and Their Ruthenium Complexes B. Schäfer, H.Görls, S.Meyer, W. Henry, J. G. Vos, S. Rau, Eur. J. Inorg. Chem., 2007, (25), 4056–4063 | |
| 27 | Merocyanine-Like Chromophores as Ligands for Catalytic Active Metals of Group VIII J. Blumhoff, R. Beckert, D. Walther, S. Rau, M. Rudolph, H. Görls, W. Plass, Eur. J. Inorg. Chem., 2007, (3), 481-486 | |
| 26 | Syntheses and Structures of Bis(4,4'-t-butyl-2,2'-bipyridine) Ruthenium(II) Complexes with functional Derivatives of Tetramethyl-bibenzimidazole A. Grüßing, S. Rau, S. Schebesta, A. Scholz, H. Görls, D. Walther, Z. Anorg. Allg. Chem., 2007, 633(7), 961-970 | |
| 25 | Inspired by nature: light driven organometallic catalysis by heterooligonuclear Ru(II) complexes S. Rau, D. Walther, J. G. Vos, Dalton Trans., 2007, (9), Frontier article 915-919 | |
| 24 | Leuchtdioden in der Chemie - Eine Hochzeit verschiedener Technologien G. Kreisel, S. Meyer, D. Tietze, T. Fidler, R. Gorges, A. Kirsch, B.Schäfer, S. Rau, Chem. Ing. Tech., 2007, 79(1-2), 153-159 | |
| 23 | Excited-state dynamics of Ru(tbbpy)32+ investigated by femtosecond time-resolved four-wave mixing B. Dietzek, D. Akimov, W. Kiefer, S. Rau, J. Popp, M. Schmitt, Laser Phys. Lett., 2007, 4(2), 121-125 | |
| 22 | Photosensitised Oxidation of citronellol in microreactors S. Meyer, D. Tietze, S. Rau, B. Schäfer, G. Kreisel, J. Photochem. Photobiol. A: Chemistry, 2007, 186(2-3), 248–253 |
2006
| 21 | A Supramolecular Photocatalyst for the Production of Hydrogen and the Selective Hydrogenation of Tolane S. Rau, B. Schäfer, D. Gleich, E. Anders, M. Rudolph, M. Friedrich, H. Görls, W. Henry, and J. G. Vos, Angew. Chem. Int. Ed., 2006, 45, 6215-6218 | |
| 20 | Dye-sensitized solar cell G. Kreisel, R. Gorges, B. Schäfer, S. Rau, S. Meyer, T. Fidler, Ger. Offen., 2006, DE 102005002942, Application: DE 2005-102005002942 | |
| 19 | Tetranuclear Complexes Containing a Luminescent Ru2M2 Core [M = CuI, (allyl)PdII]: Synthesis, Structures and Electrochemical Properties D. Walther, L. Böttcher, J. Blumhoff, S. Schebesta, H. Görls, K. Schmuck, S. Rau, M. Rudolph, Eur. J. Inorg. Chem., 2006, (12), 2385-2392 | |
| 18 | Ultrafast Excited-State Excitation Dynamics in a Quasi-Two-Dimensional Light-Harvesting Antenna Based on Ruthenium(II) and Palladium(II) Chromophores B. Dietzek, W. Kiefer, J. Blumhoff, L. Böttcher, S. Rau, D. Walther, U. Uhlemann, M. Schmitt, J. Popp, Chem. Eur. J., 2006, 12(19), 5105-5115 | |
| 17 | Synthesis of mononuclear and dinuclear ruthenium(II) tris(heteroleptic) complexes via photosubstitution in bis(carbonyl) precursors D. Mulhern, S. Brooker, H. Görls, S. Rau, J. G. Vos, Dalton Trans., 2006, 51-57 | |
| 16 | Derivatives of dipyrido[3,2-a:2',3'-c]phenazine and its ruthenium complexes, influence of arylic substitution on photophysical properties B. Schäfer, H. Görls, M. Presselt, M. Schmitt, J. Popp, W. Henry, J. G. Vos, S. Rau, Dalton Trans., 2006, (18), 2225-2231 | |
| 15 | Synthesis of new bridged biimidazoles by an acylation-dimerization sequence T. Welzel, R. Beckert, R. Fischer, S. Rau, D. Walther, H. Görls, Tetrahedron, 2006, 62(4), 731-736 | |
| 14 | Synthesis and characterisation of a series of mononuclear ruthenium(II) carbonyl complexes of heterocycle-based asymmetric bidentate ligands D. Mulhern, Y. Lan, S. Brooker, J. F. Gallagher, H. Görls, S. Rau, J. G. Vos, Inorg. Chim. Acta, 2006, 359(3), 736-744 | |
2005
| 13 | 2-Azaanthraquinones: Building Blocks for New Ring-Fused Imidazoles and their Transformation into Benzo[f]isoindole-4,9-diones B. Frank, R. Beckert, S. Rau, H. Görls, Z. Naturforsch. B, 2005, 60(7), 771-779 DOI: |
| 12 | Procedure for the production of light-emitting ruthenium(II) compounds D. Walther, S. Schebesta, S. Rau, B. Schäfer, A. Grüßing, Ger. Offen. 2005, DE 102004009551, Patent No.DE 2004-102004009551 |
2004
| 11 | Solid state structure of a rhenium bibenzimidazole complex S. Rau, H. Görls, J. Coord. Chem., 2004, 57(17-18), 1587-1590 | |
| 10 | Efficient synthesis of ruthenium complexes of the type (R-bpy)2RuCl2 and [(R-bpy)2Ru(L-L)]Cl2 by microwave-activated reactions (R: H, Me, tert-But) (L-L: substituted bibenzimidazoles, bipyrimidine, and phenanthroline) S. Rau, B. Schäfer, A. Grüßing, S. Schebesta, K. Lamm, J. Vieth, H. Görls, D. Walther, M. Rudolph, U. W. Grummt, E. Birkner, Inorg. Chim. Acta, 2004, 357(15), 4496-4503 | |
| 9 | Bi- and trinuclear oxalamidinate complexes of palladium as catalysts in the copper-free Sonogashira reaction and in the Negishi reaction S. Rau, K. Lamm, H. Görls, J. Schöffel, D. Walther, J. Organomet. Chem., 2004, 689(22), 3582-3592 | |
| 8 | Regioselective Functionalization of Tetrabromophenanthroline-Ruthenium Complexes S. Rau, R. Fischer, M. Jäger, B. Schäfer, S. Meyer, G. Kreisel, H. Görls, M. Rudolph, W. Henry, J. G. Vos, Eur. J. Inorg. Chem., 2004, (10), 2001-2003 | |
| 7 | Synthesis and characterisation of ruthenium complexes containing a pendent catechol ring L. O'Brien, M. Duati, S. Rau, A. L. Guckian, T. E. Keyes, N. M. O'Boyle, A. Serr, H. Görls, J. G. Vos, Dalton Trans., 2004, (4), 514-522 | |
1999-2003
| 6 | Efficient energy transfer in supramolecular, hydrogen-bonded polypyridylruthenium-osmium complexes S. Rau, B. Schäfer, S. Schebesta, A. Grüßing, W. Poppitz, D. Walther, M. Duati, W. R. Browne, J. G. Vos, Eur. J. Inorg. Chem., 2003, (8), 1503-1506 | |
| 5 | Simultaneous Cation/Anion Coordination by Bifunctional 1,2-Diimine/1,2-Diamine Type Ligands: Synthesis, Structures, and Properties of Tight Ion Pair Complexes of Ruthenium and Iron S. Rau, L. Böttcher, S. Schebesta, M. Stollenz, H. Görls, D. Walther, Eur. J. Inorg. Chem., 2002, (11), 2800-2809 | |
| 4 | Bis(R-bipyridyl)ruthenium bibenzimidazole complexes (R = H, Me or But): supramolecular arrangement via hydrogen bonds, photo- and electro-chemicalproperties and reactivity towards carbon dioxide S. Rau, M. Ruben, T. Büttner, C. Temme, S. Dautz, M. Rudolph, H. Görls, D. Walther, A. Bordkorb, M. Duati, C. O’Connor, J. G. Vos, Dalton Trans., 2000, (20), 3649-3657 | |
| 3 | A Bibenzimidazole-Containing Ruthenium(II) Complex Acting as a Cation-Driven Molecular Switch S. Rau, T. Büttner, C. Temme, M. Ruben, H. Görls, D. Walther, M. Duati, S. Fanni, J. G. Vos, Inorg. Chem., 2000, 39(7), 1621-1624 | |
| 2 | Novel polypyridyl ruthenium(II) complexes containing oxalamidines as ligands M. Ruben, S. Rau, A. Skirl, K. Krause, H. Görls, D. Walther, J. G. Vos, Inorg. Chim. Acta, 2000, 303(2), 206-214 | |
| 1 | Carbon dioxide and metal centres: from reactions inspired by nature to reactions in compressed carbon dioxide as solvent D. Walther, M. Ruben, S. Rau, Coord. Chem. Rev., 1999, 182(1), 67-100 | |